TEM and SNMS studies of protective alumina scales on NiCrAlY-alloys

Anal Bioanal Chem. 1996 Jun;355(5-6):703-6. doi: 10.1007/s0021663550703.

Abstract

The effect of Si addition on the oxidation behaviour of NiCrAlY alloys in the temperature range 950 bis 1100 degrees C has been investigated. During isothermal oxidation oxide growth rates were practically independent of the Si-content. However during cyclic oxidation Si additions were beneficial. Si additions of 1-2(m)/(0) appeared to shift the onset for spallation to longer times. It was found that Si stabilizes the beta-phase and probably it suppresses the formation of metastable Al(2)O(3) modifications.