Electrorheology in nanopores via lattice Boltzmann simulation

J Chem Phys. 2004 Mar 1;120(9):4492-7. doi: 10.1063/1.1644107.

Abstract

The conductance of ionic species through a cylindrical nanochannel is explored by means of a mesoscopic lattice Boltzmann numerical method. It is shown that in the absence of any external voltage, the ionic profiles develop a considerable amount of structure within the channel. The details of this structure depend on the ionic density, channel length, and Debye length. In the presence of a trans-membrane electrostatic potential, less structure is observed and Ohm's law is found to hold.