Kohn anomalies and electron-phonon interactions in graphite

Phys Rev Lett. 2004 Oct 29;93(18):185503. doi: 10.1103/PhysRevLett.93.185503. Epub 2004 Oct 28.

Abstract

We demonstrate that graphite phonon dispersions have two Kohn anomalies at the Gamma-E(2g) and K-A'1 modes. The anomalies are revealed by two sharp kinks. By an exact analytic derivation, we show that the slope of these kinks is proportional to the square of the electron-phonon coupling (EPC). Thus, we can directly measure the EPC from the experimental dispersions. The Gamma-E(2g) and K-A'1 EPCs are particularly large, while they are negligible for all the other modes at Gamma and K.