Fluorinated nanodiamond as a wet chemistry precursor for diamond coatings covalently bonded to glass surface

Yu Liu; Valery N Khabashesku; Naomi J Halas

doi:10.1021/ja042389m

Fluorinated nanodiamond as a wet chemistry precursor for diamond coatings covalently bonded to glass surface

J Am Chem Soc. 2005 Mar 23;127(11):3712-3. doi: 10.1021/ja042389m.

Authors

Yu Liu¹, Valery N Khabashesku, Naomi J Halas

Affiliation

¹ Department of Chemistry, Center for Nanoscale Science and Technology, Rice University, Houston, Texas 77005-1892, USA.

PMID: 15771502
DOI: 10.1021/ja042389m

Abstract

The chemical reaction between fluoro-nanodiamond (F-ND) powder, solubilized in o-dichlorobenzene, and a glass surface, functionalized with the silane coupling agent, 3-aminopropyltriethoxysilane (APTES), was found to proceed under heating at 130 degrees C for 24-40 h and to result in covalent bonding of F-ND particles to a glass substrate, forming a 10-40 nm thick nanocrystalline film. The observed process presents a novel and cost-effective approach to fabrication of diamond coatings on glass by using wet chemistry instead of CVD and can be extended to other materials.