Narrow (n,m)-distribution of single-walled carbon nanotubes grown using a solid supported catalyst

Sergei M Bachilo; Leandro Balzano; Jose E Herrera; Francisco Pompeo; Daniel E Resasco; R Bruce Weisman

doi:10.1021/ja036622c

Narrow (n,m)-distribution of single-walled carbon nanotubes grown using a solid supported catalyst

J Am Chem Soc. 2003 Sep 17;125(37):11186-7. doi: 10.1021/ja036622c.

Authors

Sergei M Bachilo¹, Leandro Balzano, Jose E Herrera, Francisco Pompeo, Daniel E Resasco, R Bruce Weisman

Affiliation

¹ School of Chemical Engineering and Materials Science, University of Oklahoma, 100 East Boyd Street, Norman, Oklahoma 73019, USA.

PMID: 16220926
DOI: 10.1021/ja036622c

Abstract

Unusually structure-selective growth of single-walled carbon nanotubes (SWNTs) has been attained using a CVD method with a solid supported catalyst. In this method, CO feedstock disproportionates on silica-supported catalytic nanoclusters of Co that are formed in situ from mixed salts of Co and Mo. The nanotube products are analyzed by spectrofluorimetry to reveal distributions resolved at the level of individual (n,m) structures. Two structures, (6,5) and (7,5), together dominate the semiconducting nanotube distribution and comprise more than one-half of that population. The average diameter of produced SWNTs is only 0.81 nm, and a strong propensity is found favoring chiral angles near the armchair limit.