A self-assembled hexadecanuclear 4 x[2 x 2] Mn(II)16 square grid from a pyridazine bis(hydrazone) ligand: synthesis, structure and magnetism

Subrata K Dey; Laurence K Thompson; Louise N Dawe

doi:10.1039/b611267f

A self-assembled hexadecanuclear 4 x[2 x 2] Mn(II)16 square grid from a pyridazine bis(hydrazone) ligand: synthesis, structure and magnetism

Chem Commun (Camb). 2006 Dec 21:(47):4967-9. doi: 10.1039/b611267f. Epub 2006 Oct 12.

Authors

Subrata K Dey¹, Laurence K Thompson, Louise N Dawe

Affiliation

¹ Dept of Chemistry, Memorial University, St. John's, Newfoundland, CanadaA1B 3X7.

PMID: 17136263
DOI: 10.1039/b611267f

Abstract

A compartmentalized {4 x[2 x 2]} Mn(II)16 antiferromagnetically coupled square grid results from the self-assembly reaction of a tetratopic pyridazine bis(hydrazone) ligand and Mn(II).

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Crystallography, X-Ray
Hydrazones / chemistry*
Ligands
Magnetics*
Manganese / chemistry*
Models, Molecular
Molecular Structure
Organometallic Compounds / chemical synthesis*
Organometallic Compounds / chemistry*
Pyridazines / chemistry*
Temperature

Substances

Hydrazones
Ligands
Organometallic Compounds
Pyridazines
Manganese
pyridazine