Abstract
Treatment of [Fe(2)(micro-pdt)(CO)(6)] (pdt = S(CH(2))(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe(2)(micro-pdt)(CO)(4)(phen)] (1); the protonation of with HBF(4).OEt(2) in CD(2)Cl(2) at 203 K has been monitored by (1)H NMR.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Binding Sites
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Catalysis
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Crystallography, X-Ray
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Ferric Compounds / chemistry*
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Hydrogenase / chemistry*
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Indicators and Reagents
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Iron / chemistry*
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Iron-Sulfur Proteins / chemistry*
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Phenanthrolines / chemistry*
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Sulfhydryl Compounds / chemistry*
Substances
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Ferric Compounds
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Indicators and Reagents
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Iron-Sulfur Proteins
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Phenanthrolines
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Sulfhydryl Compounds
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dithiol-iron(III)-sulfide complex
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Iron
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iron hydrogenase
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Hydrogenase
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1,10-phenanthroline