Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site

Dalton Trans. 2007 Sep 14:(34):3754-6. doi: 10.1039/b709287c. Epub 2007 Jul 16.

Abstract

Treatment of [Fe(2)(micro-pdt)(CO)(6)] (pdt = S(CH(2))(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe(2)(micro-pdt)(CO)(4)(phen)] (1); the protonation of with HBF(4).OEt(2) in CD(2)Cl(2) at 203 K has been monitored by (1)H NMR.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Binding Sites
  • Catalysis
  • Crystallography, X-Ray
  • Ferric Compounds / chemistry*
  • Hydrogenase / chemistry*
  • Indicators and Reagents
  • Iron / chemistry*
  • Iron-Sulfur Proteins / chemistry*
  • Phenanthrolines / chemistry*
  • Sulfhydryl Compounds / chemistry*

Substances

  • Ferric Compounds
  • Indicators and Reagents
  • Iron-Sulfur Proteins
  • Phenanthrolines
  • Sulfhydryl Compounds
  • dithiol-iron(III)-sulfide complex
  • Iron
  • iron hydrogenase
  • Hydrogenase
  • 1,10-phenanthroline