Efficient 1,2-addition of aryl- and alkenylboronic acids to aldehydes catalyzed by the palladium/thioether-imidazolinium chloride system

Masami Kuriyama; Rumiko Shimazawa; Ryuichi Shirai

doi:10.1021/jo7020983

Efficient 1,2-addition of aryl- and alkenylboronic acids to aldehydes catalyzed by the palladium/thioether-imidazolinium chloride system

J Org Chem. 2008 Feb 15;73(4):1597-600. doi: 10.1021/jo7020983. Epub 2008 Jan 11.

Authors

Masami Kuriyama¹, Rumiko Shimazawa, Ryuichi Shirai

Affiliation

¹ Faculty of Pharmaceutical Sciences, Doshisha Women's College of Liberal Arts, Kodo, Kyotanabe, Kyoto 610-0395, Japan. mkuriyam@dwc.doshisha.ac.jp

PMID: 18186645
DOI: 10.1021/jo7020983

Abstract

The high level of catalyst performance was attainable in the palladium-catalyzed 1,2-addition of aryl-, heteroaryl-, and alkenylboronic acids to aromatic, heteroaromatic, and aliphatic aldehydes using thioether-imidazolinium chloride L5 as a heterobidentate carbene ligand precursor.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Aldehydes / chemistry*
Boronic Acids / chemistry*
Catalysis
Imidazolines / chemistry*
Magnetic Resonance Spectroscopy
Palladium / chemistry*
Spectrometry, Mass, Electrospray Ionization
Sulfides / chemistry*

Substances

Aldehydes
Boronic Acids
Imidazolines
Sulfides
Palladium