Supramolecular PhanePhos-analogous ligands through hydrogen-bonding for asymmetric hydrogenation

Chem Commun (Camb). 2008 Feb 21:(7):844-6. doi: 10.1039/b716529c. Epub 2007 Dec 18.

Abstract

PhanePhos-analogous phosphorous ligands have been generated via self-assembly through hydrogen-bonding, and studied in rhodium-catalyzed asymmetric hydrogenation (up to 99% ee).

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Catalysis
  • Crystallography, X-Ray
  • Hydrogen Bonding
  • Hydrogenation
  • Ligands
  • Macromolecular Substances / chemical synthesis*
  • Macromolecular Substances / chemistry
  • Models, Molecular
  • Molecular Conformation
  • Organophosphorus Compounds / chemical synthesis*
  • Organophosphorus Compounds / chemistry
  • Rhodium / chemistry

Substances

  • Ligands
  • Macromolecular Substances
  • Organophosphorus Compounds
  • Rhodium