Abstract
Combining triflic acid-promoted glycosylations of trichloroacetimidates with reductive opening of benzylidene acetals with triflic acid and triethylsilane as one-pot procedures provides access to a wide range of disaccharides and 2,4- and 3,4-branched trisaccharides.
Publication types
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Research Support, N.I.H., Extramural
MeSH terms
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Acetals / chemistry*
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Benzylidene Compounds / chemistry*
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Carbohydrate Sequence
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Disaccharides / chemical synthesis
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Glycosylation
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Mesylates / chemistry
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Molecular Sequence Data
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Oligosaccharides / chemical synthesis*
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Silanes / chemistry
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Trisaccharides / chemical synthesis
Substances
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Acetals
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Benzylidene Compounds
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Disaccharides
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Mesylates
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Oligosaccharides
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Silanes
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Trisaccharides
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triethylsilane
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trifluoromethanesulfonic acid