We packed an ionic liquid (IL)-functionalized stationary phase--based on 1-octyl-3-propylimidazolium chloride covalently bounded to silica gel--into a 3.2mmx250mm column for the simultaneous separation of acidic, basic, and neutral compounds using carbon dioxide subcritical/supercritical fluid chromatography (SFC), and examined the effects of the pressure, temperature, co-solvents, and additives on the retention behavior of the analytes. The model compounds tested for SFC separation are acetaminophen, metoprolol, fenoprofen, ibuprofen, naphthalene, and testosterone. The data indicate that hydrogen-bonding and hydrophobic interactions between the analytes and the IL-modified stationary phase seem to involve in the separation process. Simultaneous separation of acidic, basic, and neutral compounds via SFC was successful at a co-solvent content of 20% MeOH, a pressure of 110 bar, and a column temperature of 35 degrees C. The relative standard deviations of the retention times and peak areas at 50 ppm were all less than 4 and 8% (n=6), respectively.