Evidence for atomic mixing via multiple intermediates during the dynamic interconversion of silicate oligomers in solution

Chem Commun (Camb). 2012 Jan 4;48(1):46-8. doi: 10.1039/c1cc14674b. Epub 2011 Oct 14.

Abstract

We investigate Si(8)- and Si(16)-based silicate species via global optimisation searches and ab initio calculations and propose a new multi-mechanism interpretation of the experimentally observed atomic mixing of silicate oligomers in solution.