Synthesis of oxazolidinones by efficient fixation of atmospheric CO2 with propargylic amines by using a silver/1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) Dual-catalyst system

Masahiro Yoshida; Tomotaka Mizuguchi; Kozo Shishido

doi:10.1002/chem.201203366

Synthesis of oxazolidinones by efficient fixation of atmospheric CO2 with propargylic amines by using a silver/1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) Dual-catalyst system

Chemistry. 2012 Dec 3;18(49):15578-81. doi: 10.1002/chem.201203366. Epub 2012 Nov 7.

Authors

Masahiro Yoshida¹, Tomotaka Mizuguchi, Kozo Shishido

Affiliation

¹ Graduate School of Pharmaceutical Sciences, The University of Tokushima, Sho-machi, Japan. yoshi@tokushima-u.ac.jp

PMID: 23135989
DOI: 10.1002/chem.201203366

Abstract

This'll fix it: efficient fixation of atmospheric CO(2) has been achieved by the reaction of propargylic amines with a silver/DBU dual-catalyst system. Various oxazolidinones were synthesized in moderate to good yields by using substituted propargylic amines.

MeSH terms

Amines
Bridged Bicyclo Compounds, Heterocyclic / chemistry*
Carbon Dioxide
Catalysis
Molecular Structure
Oxazolidinones / chemical synthesis*
Pargyline / chemistry*
Silver / chemistry*
Stereoisomerism

Substances

Amines
Bridged Bicyclo Compounds, Heterocyclic
Oxazolidinones
Carbon Dioxide
Silver
Pargyline
1,8-diazabicyclo(5.4.0)undec-7-ene