Abstract
The first synthesis of the heterocyclic marine natural product, acremolin, is reported along with the revision of the structure from a 1H-azirine to a substituted N(2),3-ethenoguanine (5-methyl-7-isopropyl-4,5-dihydroimidazo[2,1-b]purine). Additional properties of acremolin are also described including its (1)H-(15)N-HMBC and fluorescence spectra.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Acremonium / chemistry*
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Acremonium / isolation & purification
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Biological Products / chemistry*
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Fluorescent Dyes / chemistry
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Guanine / analogs & derivatives*
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Guanine / chemical synthesis
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Guanine / chemistry
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Molecular Structure
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Purines / chemical synthesis*
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Purines / chemistry
Substances
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Biological Products
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Fluorescent Dyes
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N(2),3-etheno-2'-isopropyl-1-methylguanine
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N(2),3-ethenoguanine
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N(2),3-ethenoguanine (5-methyl-7-isopropyl-4,5-dihydroimidazo(2,1-b)purine)
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Purines
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Guanine