Thermoplastic starch/polyester films: effects of extrusion process and poly (lactic acid) addition

Mater Sci Eng C Mater Biol Appl. 2013 Oct;33(7):4112-7. doi: 10.1016/j.msec.2013.05.054. Epub 2013 Jun 6.

Abstract

Biodegradable films were produced using the blown extrusion method from blends that contained cassava thermoplastic starch (TPS), poly(butylene adipate-co-terephthalate) (PBAT) and poly(lactic acid) (PLA) with two different extrusion processes. The choice of extrusion process did not have a significant effect on the mechanical properties, water vapor permeability (WVP) or viscoelasticity of the films, but the addition of PLA decreased the elongation, blow-up ratio (BUR) and opacity and increased the elastic modulus, tensile strength and viscoelastic parameters of the films. The films with 20% PLA exhibited a lower WVP due to the hydrophobic nature of this polymer. Morphological analyses revealed the incompatibility between the polymers used.

Keywords: Biodegradable film; Blown extrusion; Mechanical properties; Viscoelasticity; Water vapor permeability.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Elasticity
  • Humidity
  • Lactic Acid / chemistry*
  • Microscopy, Electron, Scanning
  • Permeability
  • Polyesters / chemistry*
  • Polymers / chemistry*
  • Starch / chemistry*
  • Steam
  • Temperature*
  • Viscosity

Substances

  • Polyesters
  • Polymers
  • Steam
  • poly(butylene adipate-co-butylene terephthalate)
  • Lactic Acid
  • poly(lactide)
  • Starch