The Freundlich adsorption isotherm constants and prediction of phosphorus bioavailability as affected by different phosphorus sources in two Kansas soils

Chemosphere. 2014 Mar:99:72-80. doi: 10.1016/j.chemosphere.2013.10.009. Epub 2013 Nov 13.

Abstract

Phosphorus (P) adsorption onto soil constituents influences P bioavailability from both agronomic and environmental perspectives. In this study, the P availability from different P sources along with utility of Freundlich adsorption coefficients on the predictability of various crop growth parameters were assessed. Two soils were amended with 150mgPkg(-1) each from six different P sources comprised of manures from two types of ruminants animals, three types of monogastric animals, and inorganic P fertilizer. Corn (Zea mays) was grown and harvested seven times under greenhouse conditions to remove P from the P amended treatments. The application of all P sources reduced the value of Freundlich K and increased the value of Freundlich 1/n and equilibrium P concentration (EPC0) in both soils compared to the un-amended control before cropping. The swine (Sus scrofa) manure (HM) resulted in significant smaller values of Freundlich K and larger values of 1/n in the P deficient Eram-Lebo soil compared to other P sources while, the opposite was true for the turkey (Meleagris gallopava) litter (TL) in the Ulysses soil. The corn biomass, tissue P concentration and P uptake were significantly influenced by all P sources during the first harvest and the total P uptake during seven harvests in both soils compared to the control treatment. Both Freundlich coefficients had strong relationships with the aforementioned corn parameters in the P deficient Eram-Lebo soil while, strength of the association was weak or missing in the Ulysses soil which had optimum levels of antecedent P.

Keywords: Animal manure phosphorus; Corn phosphorus uptake; Freundlich adsorption coefficients; Soil phosphorus bioavailability.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Animals
  • Biomass
  • Fertilizers / statistics & numerical data
  • Kansas
  • Manure
  • Models, Chemical*
  • Phosphorus / analysis*
  • Phosphorus / chemistry
  • Soil / chemistry*
  • Soil Pollutants / analysis*
  • Soil Pollutants / chemistry
  • Swine
  • Zea mays / growth & development

Substances

  • Fertilizers
  • Manure
  • Soil
  • Soil Pollutants
  • Phosphorus