Fluorogel elastomers with tunable transparency, elasticity, shape-memory, and antifouling properties

Angew Chem Int Ed Engl. 2014 Apr 22;53(17):4418-22. doi: 10.1002/anie.201310385. Epub 2014 Mar 18.

Abstract

Omniphobic fluorogel elastomers were prepared by photocuring perfluorinated acrylates and a perfluoropolyether crosslinker. By tuning either the chemical composition or the temperature that control the crystallinity of the resulting polymer chains, a broad range of optical and mechanical properties of the fluorogel can be achieved. After infusing with fluorinated lubricants, the fluorogels showed excellent resistance to wetting by various liquids and anti-biofouling behavior, while maintaining cytocompatiblity.

Keywords: antifouling; omniphobic surface; polymer gel; shape memory; surface chemistry.