Spectroscopic characterization of magnetic Fe3O4@Au core shell nanoparticles

Spectrochim Acta A Mol Biomol Spectrosc. 2015 Apr 5:140:392-7. doi: 10.1016/j.saa.2014.12.097. Epub 2015 Jan 14.

Abstract

The magnetic nanoparticles iron oxide (Fe3O4) nanoparticles and iron oxide/gold core-shell (Fe3O4/Au) nanoparticles were synthesized and their catalytic photo-degradation activity towards malathion as example of organophosphorus pesticides were reported. Iron oxide (Fe3O4) magnetic nanoparticle was successfully prepared through co-precipitation method by the reduction of ferric chloride (FeCl3) using ascorbic acid. The morphology of the prepared nanoparticles was characterized by the TEM and XRD (X-ray diffraction) techniques. Degradation of 10 ppm of malathion in the presence of these nanoparticles under UV radiation was monitored using (HPLC) and UV-visible spectra. Fe3O4/Au nanoparticles showed higher efficiency in photo-degradation of malathion than Fe3O4 ones.

Keywords: Electron microscopy; Magnetic properties; Nanostructures.

MeSH terms

  • Ferrosoferric Oxide / chemistry*
  • Gold / chemistry*
  • Magnetite Nanoparticles / chemistry*
  • Magnetite Nanoparticles / ultrastructure
  • Malathion / chemistry
  • Photolysis
  • Spectrophotometry, Ultraviolet
  • X-Ray Diffraction

Substances

  • Magnetite Nanoparticles
  • Gold
  • Malathion
  • Ferrosoferric Oxide