Ultra-Fast Layer-by-Layer Approach for Depositing Flame Retardant Coatings on Flexible PU Foams within Seconds

ACS Appl Mater Interfaces. 2016 Mar;8(10):6315-9. doi: 10.1021/acsami.6b00598. Epub 2016 Mar 3.

Abstract

In this letter, we are presenting a novel approach for the deposition of layer-by-layer (LbL) coatings capable of conferring flame retardant properties to flexible polyurethane foams exploiting subsecond deposition times. The process yields nanoscale coatings able to reduce by 33% one of the main fire safety parameters, namely the heat release rate peak, with a total treatment time of only 2.5 s. This new approach turned out to be three to 4 orders of magnitude faster than conventional LbL treatments. Such results make it possible for the exploit of LbL as a competitive, efficient and ecofriendly technology at industrial scale.

Keywords: chitosan; cone calorimetry; fast deposition; flame retardancy; layer by layer; polyurethane foams.