2D Layered Materials of Rare-Earth Er-Doped MoS2 with NIR-to-NIR Down- and Up-Conversion Photoluminescence

Adv Mater. 2016 Sep;28(34):7472-7. doi: 10.1002/adma.201601833. Epub 2016 Jun 20.

Abstract

A 2D system of Er-doped MoS2 layered nanosheets is developed. Structural studies indicate that the Er atoms can be substitutionally introduced into MoS2 to form stable doping. Density functional theory calculation implies that the system remains stable. Both NIR-to-NIR up-conversion and down-conversion light-emissions are observed in 2D transition metal dichalcogenides, ascribed to the energy transition from Er(3+) dopants.

Keywords: 2D materials; photoluminescence; rare-earth ions; substitution doping; up-conversion.