Metabolome based volatiles profiling in 13 date palm fruit varieties from Egypt via SPME GC-MS and chemometrics

Food Chem. 2017 Feb 15:217:171-181. doi: 10.1016/j.foodchem.2016.08.089. Epub 2016 Aug 25.

Abstract

Dates (Phoenix dactylifera L.) are distributed worldwide as major food complement providing a source of sugars and dietary fiber as well as macro- and micronutrients. Although phytochemical analyses of date fruit non-volatile metabolites have been reported, much less is known about the aroma given off by the fruit, which is critical for dissecting sensory properties and quality traits. Volatile constituents from 13 date varieties grown in Egypt were profiled using SPME-GCMS coupled to multivariate data analysis to explore date fruit aroma composition and investigate potential future uses by food industry. A total of 89 volatiles were identified where lipid-derived volatiles and phenylpropanoid derivatives were the major components of date fruit aroma. Multivariate data analyses revealed that 2,3-butanediol, hexanal, hexanol and cinnamaldehyde contributed the most to classification of different varieties. This study provides the most complete map of volatiles in Egyptian date fruit, with Siwi and Sheshi varieties exhibiting the most distinct aroma among studied date varieties.

Keywords: GC–MS; Phoenix dactylifera; Principal component analysis; SPME; Volatiles.

MeSH terms

  • Acrolein / analogs & derivatives
  • Acrolein / analysis
  • Aldehydes / analysis
  • Butylene Glycols / analysis
  • Dietary Fiber / analysis
  • Egypt
  • Fruit / chemistry
  • Gas Chromatography-Mass Spectrometry*
  • Hexanols / analysis
  • Metabolome*
  • Multivariate Analysis
  • Nutritive Sweeteners / analysis
  • Phoeniceae / chemistry*
  • Phoeniceae / classification
  • Principal Component Analysis
  • Solid Phase Extraction*
  • Volatile Organic Compounds / analysis*

Substances

  • Aldehydes
  • Butylene Glycols
  • Dietary Fiber
  • Hexanols
  • Nutritive Sweeteners
  • Volatile Organic Compounds
  • 2,3-butylene glycol
  • Acrolein
  • n-hexanal
  • cinnamaldehyde