Ultraflexible Transparent Film Heater Made of Ag Nanowire/PVA Composite for Rapid-Response Thermotherapy Pads

ACS Appl Mater Interfaces. 2017 Feb 22;9(7):6644-6651. doi: 10.1021/acsami.6b16853. Epub 2017 Feb 9.

Abstract

Ultraflexible transparent film heaters have been fabricated by embedding conductive silver (Ag) nanowires into a thin poly(vinyl alcohol) film (AgNW/PVA). A cold-pressing method was used to rationally adjust the sheet resistance of the composite films and thus the heating powers of the AgNW/PVA film heaters at certain biases. The film heaters have a favorable optical transmittance (93.1% at 26 Ω/sq) and an outstanding mechanical flexibility (no visible change in sheet resistance after 10 000 bending cycles and at a radius of curvature ≤1 mm). The film heaters have an environmental endurance, and there is no significant performance degradation after being kept at high temperature (80 °C) and high humidity (45 °C, 80% humidity) for half a year. The efficient Joule heating can increase the temperature of the film heaters (20 Ω/sq) to 74 °C in ∼20 s at a bias of 5 V. The fast-heating characteristics at low voltages (a few volts) associated with its transparent and flexibility properties make the poly(dimethylsiloxane)/AgNW/PVA composite film a potential candidate in medical thermotherapy pads.

Keywords: AgNW/PVA film heater; cold pressing; environmental endurance; thermal response; thermotherapy pad; transparent; ultraflexible.

MeSH terms

  • Electric Conductivity
  • Hardness
  • Hot Temperature
  • Hyperthermia, Induced
  • Membranes, Artificial
  • Nanowires*
  • Oxidation-Reduction
  • Silver
  • Surface Properties

Substances

  • Membranes, Artificial
  • Silver