Comparison of tetrel bonds in neutral and protonated complexes of pyridineTF₃ and furanTF₃ (T = C, Si, and Ge) with NH₃

Ab initio calculations have been performed for the complexes H⁺-PyTX₃NH₃ and H⁺-furanTF₃NH₃ (T = C, Si, and Ge; X = F and Cl) with focus on geometries, energies, orbital interactions, and electron densities to study the influence of protonation on the strength of tetrel bonding. The primary interaction mode between α/β-furanCF₃/p-PyCF₃ and NH₃ changes from an FH hydrogen bond to a CN tetrel bond as a result of protonation. Importantly, the protonation has a prominent enhancing effect on the strength of tetrel bonding with an increase in binding energy from 14 to 30 kcal mol^-1. The tetrel bonding becomes stronger in the order H⁺-p-PySiF₃NH₃ < H⁺-m-PySiF₃NH₃ < H⁺-o-PySiF₃NH₃, showing a reverse trend from that of the neutral analogues. In addition, there is competition between the tetrel and hydrogen bonds in the protonated complexes, in which the hydrogen bond is favored in the complexes of H⁺-p-PyCF₃ but the tetrel bond is preferred in the complexes of H⁺-p-PyTX₃ (T = Si, Ge; X = F, Cl) and H⁺-o/m-PySiF₃.