Applications of ZnO in photodetectors are limited by the great quantity of extrinsic majority carriers due to structural defects and difficult exciton dissociation due to the large exciton binding energy; these generally lead to a higher dark current (Id) and lower light current (Il), severely degrading the responsivity and detectivity. C dots are incorporated into an annealing-free ZnO layer to innovatively construct a local built-in electric field (Ebi) using the difference in the work functions; this simultaneously overcomes the drawbacks of the pristine ZnO photosensitive layer. In dark, the extrinsic majority carrier of ZnO is depleted around the incorporated C dots due to the self-depleting effect; thus, the Id decreases. Under UV illumination, the photogenerated exciton driven by the local Ebi is easily dissociated into a free charge carrier, contributing to the improved Il. This study paves a universal way to effectively improve the detection characteristics of photoconductive devices by incorporating the local Ebi.