Novel MoS₂-DOPO Hybrid for Effective Enhancements on Flame Retardancy and Smoke Suppression of Flexible Polyurethane Foams

A novel MoS₂-DOPO hybrid has been successfully synthesized through the grafting of 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) on the surface of MoS₂ nanosheets using allyl mercaptan as an intermediate. MoS₂-DOPO was used as a flame retardant additive to prepare flame-retardant flexible polyurethane foam (FPUF). The influence of MoS₂-DOPO on the mechanical, thermal stability, and flame retardancy properties of FPUF composites were systematically investigated. The incorporation of MoS₂-DOPO could not deteriorate greatly the tensile strength and 50% compression set of FPUF composites, but effectively improves the char residue. The cone calorimeter and smoke density tests results revealed that the peak heat release rate, total heat release, and the maximum smoke density of the MoS₂-DOPO/FPUF composite were reduced by 41.3, 27.7, and 40.5%, respectively, compared with those of pure FPUF. Furthermore, the char residue after cone calorimeter tests and pyrolysis gaseous products of the MoS₂-DOPO/FPUF composite were analyzed by scanning electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, and thermogravimetric analysis/infrared spectrometry. The results suggested that the MoS₂-DOPO hybrid played a synergistic flame retardant effect of gas and condensed bi-phase action. In addition, a possible flame retardancy and smoke suppression mechanism of the MoS₂-DOPO/FPUF composite were proposed. This study provides a facile and promising strategy for the fabrication of polymer materials with excellent flame retardancy and smoke suppression properties.