Ammonia capture from human urine to harvest liquid N-P compound fertilizer by a submerged hollow fiber membrane contactor: Performance and fertilizer analysis

In this study, we developed a submerged hollow fiber membrane contactor (HFMC) to recover ammonia from human urine to get compound N-P fertilizers. The ammonia capture performance, water vapor transmembrane performance, ion rejection performance and the liquid fertilizer components using 1-4 mol/L H₃PO₄ as the stripping solution was comprehensively investigated. Increasing H₃PO₄ concentration did not significantly affect the ammonia capture performance but the water vapor transfer and fertilizer components. The ammonia mass transfer coefficients were in a range of 1.95×10^-6±4.77×10^-8 to 2.28×10^-6±6.71×10^-8 m/s and the ammonia flux fluctuated between 17.80 and 20.80 g/m²·h. The water vapor flux increased with the increase of stripping solution concentration and the time elapsed. The N content (21.29-55.24 g/L) was in the range of the commercial products while the P₂O₅ content (99.41-281 g/L) was slightly higher, which can be used in the soils or plants with a high demand for phosphorus. The liquid fertilizers were all mixtures of (NH₄)₂HPO₄ and NH₄H₂PO_4, but the distribution ratio slightly changed with the different initial H₃PO₄ concentration. The economic assessment showed that harvesting liquid N-P fertilizer from human urine using HFMC can make a profit of $7.089/L.