Bisphenol A cleanup over MIL-100(Fe)/CoS composites: Pivotal role of Fe-S bond in regenerating Fe²⁺ ions for boosted degradation performance

Series of MIL-100(Fe)/CoS composites (MxCy) were facilely fabricated using ball-milling method. The optimum M50C50 exhibited extremely higher Fenton-like catalytic degradation activity toward bisphenol A (BPA) than the pristine MIL-100(Fe) and CoS. The significant improvement of BPA degradation was attributed to the synergetic effect between MIL-100(Fe) and CoS with the synergistic factor being 95.7%, in which the Fe-S bonds formed at the interface of the two components facilitate the Fe³⁺/Fe²⁺ cycle by improving the electron mobility both from Co to Fe and from S to Fe. Furthermore, the influence factors like co-existing inorganic ions and pH values on the catalysis activity of M50C50 were explored. The possible reaction mechanism was proposed and confirmed by both active species capture tests and electron spin resonance (ESR) determinations. It was found that M50C50 demonstrated good reusability and water stability, in which the morphology and structure were not changed obviously after five runs' operation. To our best knowledge, it is the first work concerning the interfacial interaction of Fe-MOF/MSx to promote Fe³⁺/Fe²⁺ cycle in Fe-MOFs for the purpose of organic pollutants degradation in the Fenton-like AOPs system.