Effect of Polyethylene Glycol and Activated Carbon Macroparticles on Thermal Conductivity of Paraffin Wax for Thermal Storage Applications

Polymers (Basel). 2022 Oct 5;14(19):4181. doi: 10.3390/polym14194181.

Abstract

Low thermal conductivity is the major obstacle for the wide range utilization of phase change materials (PCMs), especially organic PCMs, for most practical applications in thermal engineering. This study investigates the potential of enhancing the charging and discharging rates of organic PCM (RT44HC) by introducing polyethylene glycol (PEG) and activated carbon macroparticles (ACMPs). Different concentrations of PEG and ACMPs ranging from 0.3 wt% to 2 wt% were tested separately. The optimized concentrations found were used as dual reinforcements to attain the highest possible thermal conductivity. The specimens were tested for a complete charging-discharging cycle using an improvised thermal apparatus. Use of ACMP alone resulted in a minimal reduction in complete charging-discharging time due to the settlement of ACMPs at the bottom after 2-3 heating-cooling cycles. However, the addition of PEG with ACMPs exhibited a reduction in charging-discharging time due to the formation of a stable dispersion. PEG served as a stabilizing agent for ACMPs. The lowest charging-discharging time of 180 min was exhibited by specimens containing 1 wt% PEG and 0.5 wt% ACMPs which is 25% lower compared to bare PCM.

Keywords: activated carbon macroparticles (ACMPs); organic PCM (RT44HC); phase hange materials (PCM); polyethylene glycol (PEG).

Grants and funding

This research was funded by King Khalid University through Research Center for Advanced Materials Science (RCAMS) and Japan International Cooperation Agency for AUN/SEED-Net on Collaboration Education Program UM CEP 1901, Japan ASEAN Collaborative Education Program (JACEP) under grant no: RCAMS/KKU/0010/21 and UM CEP 1901. And The APC was funded by King Khalid University and Jesus’s Scientific Consultancy of Industrial and Academic Research.