Enhancement of perovskite-based solar cells employing core-shell metal nanoparticles

Nano Lett. 2013 Sep 11;13(9):4505-10. doi: 10.1021/nl4024287. Epub 2013 Aug 19.

Abstract

Recently, inorganic and hybrid light absorbers such as quantum dots and organometal halide perovskites have been studied and applied in fabricating thin-film photovoltaic devices because of their low-cost and potential for high efficiency. Further boosting the performance of solution processed thin-film solar cells without detrimentally increasing the complexity of the device architecture is critically important for commercialization. Here, we demonstrate photocurrent and efficiency enhancement in meso-superstructured organometal halide perovskite solar cells incorporating core-shell Au@SiO2 nanoparticles (NPs) delivering a device efficiency of up to 11.4%. We attribute the origin of enhanced photocurrent to a previously unobserved and unexpected mechanism of reduced exciton binding energy with the incorporation of the metal nanoparticles, rather than enhanced light absorption. Our findings represent a new aspect and lever for the application of metal nanoparticles in photovoltaics and could lead to facile tuning of exciton binding energies in perovskite semiconductors.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Calcium Compounds / chemistry*
  • Gold / chemistry
  • Metal Nanoparticles / chemistry*
  • Oxides / chemistry*
  • Quantum Dots / chemistry*
  • Semiconductors
  • Silicon Dioxide / chemistry
  • Solar Energy
  • Solutions / chemistry
  • Sunlight
  • Titanium / chemistry*

Substances

  • Calcium Compounds
  • Oxides
  • Solutions
  • perovskite
  • Gold
  • Silicon Dioxide
  • Titanium