Catalytic biorefining of plant biomass to non-pyrolytic lignin bio-oil and carbohydrates through hydrogen transfer reactions

Angew Chem Int Ed Engl. 2014 Aug 11;53(33):8634-9. doi: 10.1002/anie.201403747. Epub 2014 Jun 11.

Abstract

Through catalytic hydrogen transfer reactions, a new biorefining method results in the isolation of depolymerized lignin--a non-pyrolytic lignin bio-oil--in addition to pulps that are amenable to enzymatic hydrolysis. Compared with organosolv lignin, the lignin bio-oil is highly susceptible to further hydrodeoxygenation under low-severity conditions and therefore establishes a unique platform for lignin valorization by heterogeneous catalysis. Overall, the potential of a catalytic biorefining method designed from the perspective of lignin utilization is reported.

Keywords: biorefinery; catalytic hydrogen transfer; cellulose; enzymatic hydrolysis; lignin.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • 2-Propanol / chemistry
  • Biomass*
  • Catalysis
  • Endo-1,4-beta Xylanases / metabolism
  • Hydrogen / chemistry
  • Hydrolysis
  • Lignin / chemistry*
  • Lignin / metabolism*
  • Nickel / chemistry
  • Plants / metabolism

Substances

  • Nickel
  • Hydrogen
  • Lignin
  • Endo-1,4-beta Xylanases
  • 2-Propanol