In this study, the rheology, fluidity, stability, and time-varying properties of cement paste with different substitute contents of silica fume (SF) were investigated. The result showed that the effects of SF on macro-fluidity and micro-rheological properties were different under different water-cement ratios. The addition of SF increased the yield stress and plastic viscosity in the range of 2.61-18.44% and 6.66-24.66%, respectively, and reduced the flow expansion in the range of 4.15-18.91%. The effect of SF on cement paste gradually lost its regularity as the w/c ratio increased. The SF can effectively improve the stability of cement paste, and the reduction range of bleeding rate was 0.25-4.3% under different water-cement ratios. The mathematical models of rheological parameters, flow expansion, and time followed the following equations: τ(t) = τ0 + k0t, η(t) = η0eat, and L(t) = L0 - k1t, L(t) = L0 - k1t - a1t2. The SF slowly increased the rheological parameters in the initial time period and reduced the degree of fluidity attenuation, but the effect was significantly enhanced after entering the accelerated hydration period. The mechanism of the above results was that SF mainly affected the fluidity and rheology of the paste through the effect of water film thickness. The small density of SF particles resulted in a low sedimentation rate in the initial suspended paste, which effectively alleviated the internal particle agglomeration effect and enhanced stability. The SF had a dilution effect and nucleation effect during hydration acceleration, and the increase of hydration products effectively increased the plastic viscosity.
Keywords: fluidity; micromechanism; rheology; silica fume (SF); stability; water film thickness.