Role of Nanocrystallites of Al-Based Glasses and H₂O₂ in Degradation Azo Dyes

Al-based metallic glasses have a special atomic structure and should have a unique degradation ability in azo dye solutions. The Al₈₈Ni₉Y₃ (Y3), Al₈₅Ni₉Y₆ (Y6) and Al₈₂Ni₉Y₉ (Y9) glassy ribbons are melt spun and used in degrading methyl orange (MO) azo dye solution with adding H₂O₂. With increasing c_Y, the as-spun ribbons have an increasing GFA (glass formability) and gradually decreased the degradation rate of MO solution. TEM (transmission electron microscopy) results show that the Y3 ribbon has nano-scale crystallites, which may form the channels to transport elements to the surface for degrading the MO solution. After adding H₂O₂, the degradation efficiency of Al-based glasses is improved and the Y6 ribbon has formed nano-scale crystallites embedded in the amorphous matrix and it has the largest improvement in MO solution degradation. These results indicate that forming nano-scale crystallites and adding H₂O₂ are effective methods to improve the degradation ability of Al-based glasses in azo dye solutions.